Researchers develop graphene membranes with pyridinic-nitrogen at pore edges for high-performance CO2 capture

Researchers at École Polytechnique Fédérale de Lausanne (EPFL) have developed advanced graphene membranes with pyridinic-nitrogen at pore edges, reportedly showing unprecedented performance in CO2 capture. This could mark a step towards more efficient carbon capture technologies.

Carbon capture, utilization, and storage (CCUS) is a technology that reduces carbon dioxide (CO2) emissions from hard-to-abate industrial sources such as power plants, cement factories, steel mills, and waste incinerators. But current capture methods rely on energy-intensive processes, which makes them costly and unsustainable. Researchers are working to develop membranes that can selectively capture CO2 with high efficiency, thereby reducing the energy and financial costs associated with CCUS. But even state-of-the-art membranes, such as polymer thin films, are limited in terms of CO2 permeance and selectivity, which limits their scalability. So, the challenge is to create membranes that can simultaneously offer high CO2 permeance and selectivity, crucial for effective carbon capture.


The team of scientists, led by Kumar Varoon Agrawal at EPFL, has now made a breakthrough in this area by developing membranes that show exceptional CO2 capture performance by incorporating pyridinic nitrogen at the edges of graphene pores. The membranes strike a remarkable balance of high CO2 permeance and selectivity, making them highly promising for various industrial applications. 

The researchers began by synthesizing single-layer graphene films using chemical vapor deposition on copper foil. They introduced pores into the graphene through controlled oxidation with ozone, which formed oxygen-atom functionalized pores. They then developed a method to incorporate nitrogen atoms at the pore edge in the form of pyridinic N by reacting the oxidized graphene with ammonia at room temperature.

The researchers confirmed the successful incorporation of pyridinic nitrogen and the formation of CO2 complexes at the pore edges by using various techniques, such as X-ray photoelectron spectroscopy and scanning tunneling microscopy. The incorporation of pyridinic N remarkably improved the binding of CO2 on graphene pores.

The resulting membranes showed a high CO2/N2 separation factor, with an average of 53 for a gas stream containing 20% CO2. Remarkably, streams with about 1% CO2, achieved separation factors above 1000 because of the competitive and reversible binding of CO2 at the pore edges, facilitated by the pyridinic nitrogen.

The scientists also showed that the membrane preparation process is scalable, producing high-performance membranes on a centimeter scale. This is crucial for practical applications, meaning that the membranes can be deployed in large-scale industrial settings.

The high performance of these graphene membranes in capturing CO2, even from dilute gas streams, can significantly reduce the costs and energy requirements of carbon capture processes. This innovation opens new avenues in the field of membrane science, potentially leading to more sustainable and economical CCUS solutions.

The uniform and scalable chemistry used in creating the membranes means that they can be scaled-up soon. The team is now looking to produce these membranes by a continuous roll-to-roll process. 

Posted: Jun 25,2024 by Roni Peleg